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Capacity Fade of a Lithium-Ion Battery

Application ID: 12667


Side reactions and degradation processes may lead to a number of undesirable effects, causing capacity loss in lithium-ion batteries. Typically, aging occurs due to multiple complex phenomena and reactions that occur simultaneously at different places in the battery, and the degradation rate varies between certain stages during a load cycle, depending on potential, local concentration, temperature, and the direction of the current. Different cell materials age differently, and the combination of different materials may result in further accelerated aging due to, for instance, “crosstalk” electrode materials.

This tutorial demonstrates how to model aging in the negative graphite electrode in a lithium-ion battery, where a parasitic solid-electrolyte-interface (SEI) forming reaction results in an irreversible loss of cycleable lithium. The model also includes the effect of increasing potential losses due to the resistance of the growing SEI film on the electrode particles, as well as the effect of a reduced electrolyte volume fraction on the electrolyte charge transport.

This application was built using the following:

Batteries & Fuel Cells Module

The combination of COMSOL® products required to model your application depends on the physics interfaces that define it. Particular physics interfaces may be common to several products (see the Specification Chart for more details). To determine the right combination of products for your project, you should evaluate all of your needs in light of each product's capabilities, consultation with the COMSOL Sales and Support teams, and the use of an evaluation license.