Screening Effects in Probing the Electric Double Layer by Scanning Electrochemical Potential Microscopy
R.F. Hamou, P.U. Biedermann, A. Erbe, and M. Rohwerder
Max-Planck-Institut für Eisenforschung GmbH, Düsseldorf, Germany
A computational method is developed to study probing the electric double layer by Scanning Electrochemical Potential Microscopy. The model is based on a modified Poisson- Boltzmann equation, which takes into account steric effects. We investigated the effect of metallic apex protrusion and the Open Circuit Potential (OCP) of the tip on the probed potential. A clear electrostatic screening effect ...
P. Fodor, and J. D'Alessandro
Dept. of Physics
Cleveland State University
In this work a miniaturized fuel cell design based on microchannels, into which the liquid fuel and oxidizer streams are fed through T shaped connectors, is optimized for improved fuel usage. This particular design exploits the laminar nature of the fluid flow at small Reynolds numbers to keep the fuel and oxidizer confined in the vicinity of the corresponding electrodes without the need of a ...
Optimization of the Lithium Insertion Cell with Silicon Negative Electrode for Automotive Applications
R. Chandrasekaran, and A. Drews
Research and Advanced Engineering
Ford Motor Company
The US Advanced Battery Consortium (USABC) has established goals for long term commercialization of advanced batteries for electric vehicle applications. In this work, a dual lithium-ion insertion cell with silicon as the negative electrode and an intercalation material as the positive electrode is modeled using COMSOL Multiphysics. Both are composite porous electrodes with binder, void ...
Modeling a Non-Flooding Hybrid Polymer Electrolyte Fuel Cell and Related Diffusion-Migration-Reaction Systems
B.E. McNealy, J.L. Hertz
University of Delaware, Newark, DE, USA
Introduction: Understanding the mass and charge transport behavior of heterogeneous systems that include diffusion, migration, and reaction of ions is important in fuel cells, batteries, and other electrochemical applications. Here, a numerical model for charged species transport and reaction has been developed to simulate the electrochemical behavior of a novel type of “non-flooding” hybrid ...
E. Firat, G. Bandlamudi, M. Crisogianni, P. Beckhaus, A. Heinzel
Centre for Fuel Cell Technology (ZBT), Duisburg,NRW, Germany
Heat management is crucial for the satisfactory operation of HT-PEM (High temperature polymer-electrolyte-membrane) fuel cells. Current work investigates the use of heat pipes in a HT PEMFC stack consisting of 24 cells, each with an active area of 300 cm^2. Heat pipes are known to be thermal superconductors operating on the principles of high convective heat transfer and phase transition. ...
Hörmann, Johannes (何约翰) , Meng, Yonggang (孟永钢) ,
 State Key Laboratory of Tribology, Tsinghua University, Beijing, China
In solution, sodium dodecyl sulfate (SDS) (structure shown in Fig. 1) can form a boundary film on metal surfaces. Previous studies have extensively investigated the characteristics of such surfactant films experimentally . A dependency of SDS surface concentration and film structure on the metal's electric potential has been demonstrated, in aqueous as well as in non-aqueous solutions. ...
Current Density Simulations in the Electrodeposition from Ionic Liquids: Effects of the Conductivity
I. Perissi, C. Borri, S. Caporali, and A. Lavacchi
Department of Chemistry, University of Firenze, Sesto Fiorentino, FI, Italy
The overall goal of this work is the use of COMSOL Multiphysics® in the modeling of the current density distributions for the electrodeposition of aluminum coatings from ionic liquids. The local current distribution is strongly dependant on the conductivity and on the geometry of the galvanic cell and can only be computed by the numerical solution of the partial differential equations ...
B. Bozzini, S. Maci, I. Sgura, R. Lo Presti, and E. Simonetti
Dipartimento di Ingegneria dell’Innovazione, Università del Salento, Lecce, Italy
Dipartimento di Matematica, Università del Salento, Lecce, Italy
ENEA Casaccia, Dipartimento TER, Centro Ricerche Casaccia, S. Maria di Galeria, Roma, Italy
This paper describes the numerical modeling of a key material-stability issue within the realm of Molten Carbonate Fuel Cells (MCFC). The model describes the morphological and attending electrocatalytic evolution of porous NiO electrodes and is apt to predict electrochemical observables that can be recorded during Fuel Cell operation. The model has been validated with original experimental data ...
L. Lam, and R. Darling
University of Washington
Many physical systems contain sequential modes of operation. The sequence is one-way and switching between modes is dependent upon specific internal parameters of the system itself. While COMSOL provides the flexibility to perform time-domain simulation and time-based modifications of boundary conditions, simulating sequential systems based upon internal physical variables in COMSOL can be a ...
A.V. Volkov, K. Tybrandt, I.V. Zozoulenko, M. Berggren
Organic Electronics, ITN, Linköping University, Norrköping, Sweden
Modeling of an ion bipolar junction transistor (IBJT) is performed using the COMSOL Multiphysics® software. Our model describes the IBJT which was developed and characterized . The IBJT under consideration consists of an anion-selective collector and emitter, a cation-selective base and a neutral junction. The physical model is based on Poisson and Nernst-Planck (PNP) equations. A two ...